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Stereoselective and controlled polymerization of D,L-lactide using indium(III) trichloride
Journal article   Peer reviewed

Stereoselective and controlled polymerization of D,L-lactide using indium(III) trichloride

Agostino Pietrangelo, Marc A. Hillmyer and William B. Tolman
Chemical communications (Cambridge, England), (19), pp.2736-2737
01/01/2009
PMID: 19532938

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Indium trichloride, benzyl alcohol, and triethylamine (without an added 'directing' multidentate ligand) generate a catalyst in situ for the room temperature polymerization of D, L-lactide affording highly heterotactic polylactide of controlled molecular weight and narrow molecular weight distribution.

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