Abstract
While a 1:1 Cu-O2 adduct is generally unreactive with organic substrates, phosphines displace O2 via an associative process and added Cu(I) leads to a novel internal ligand oxidation to yield a Cu(II)-o-iminosemiquinone complex.
- Title
- Reactivity of a 1:1 copper-oxygen complex: isolation of a Cu(II)-o-iminosemiquinonato species
- Author/Creator
- Anne M Reynolds - University of MinnesotaElizabeth A Lewis - University of MinnesotaNermeen W Aboelella - University of MinnesotaWilliam B Tolman - University of Minnesota
- Publication Details
- Chemical communications (Cambridge, England), (15), pp.2014-2016
- Academic Unit
- College of Arts and Sciences; Chemistry
- Language
- English
- Resource Type
- Journal article
- Record Identifier
- 991015177310203691