Abstract
Truncated, correlated, wave function methods either produce imaginary frequencies (in the extreme case) or nonphysically low frequencies in out-of-plane motions for carbon and adjacent atoms when the carbon atoms engage in pi bonding. Cyclopropenylidene is viewed as the simplest aromatic hydrocarbon, and the present as well as previous theoretical studies have shown that this simple molecule exhibits this behavior in the two out-of-plane bends (OPBs). This nonphysical behavior has been treated by removing nearly linear dependent basis functions according to eigenvalues of the overlap matrix, by employing basis sets where the spd space saturatation is balanced with higher angular momentum functions, by including basis set superposition/incompleteness error (BSSE/BSIE) corrections, or by combining standard correlation methods with explicitly correlated methods to produce hybrid potential surfaces. However, this work supports the recently described hypothesis that the OPB problem is both a method and a basis set effect. The correlated wave function's largest higher-order substitution term comes from a pi -> pi* excitation where constructive interference of both orbitals artificially stabilizes the OPB. By employing schema to overcome this issue, the symmetric OPB v(9) is the predicted to be the second-brightest transition, and it will be observed very close to 775 cm(-1). However, more work from the community is required to formulate better how carbon atoms interact with their adjacent atoms in pi-bonded systems. Such bonds are ubiquitous in all of chemistry and beyond.