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Mixed metal bis(mu-oxo) complexes with [CuM(mu-O)2]n+(M = Ni(III) or Pd(II)) cores
Journal article   Peer reviewed

Mixed metal bis(mu-oxo) complexes with [CuM(mu-O)2]n+(M = Ni(III) or Pd(II)) cores

Nermeen W Aboelella, John T York, Anne M Reynolds, Koyu Fujita, Christopher R Kinsinger, Christopher J Cramer, Charles G Riordan and William B Tolman
Chemical communications (Cambridge, England), (15), pp.1716-1717
08/07/2004
DOI: https://doi.org/10.1039/B404640D
PMID: 15278152

Abstract

Copper - chemistry Hydrogen Peroxide Nickel - chemistry Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction Palladium - chemistry
Two highly reactive heterodinuclear bis(mu-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at -80 degrees C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.

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