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Intermediates in Reactions of Copper(I) Complexes with N-Oxides: From the Formation of Stable Adducts to Oxo Transfer
Journal article   Peer reviewed

Intermediates in Reactions of Copper(I) Complexes with N-Oxides: From the Formation of Stable Adducts to Oxo Transfer

Sungjun Hong, Aalo K. Gupta and William B. Tolman
Inorganic chemistry, Vol.48(14), pp.6323-6325
07/20/2009
DOI: https://doi.org/10.1021/ic900435p
PMCID: PMC2878392
PMID: 19425587

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
Reactions of copper(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel copper(I) N-oxide adducts, aryl substituent hydroxylation, and bis (mu-oxo)dicopper complex formation via a route involving oxo transfer.

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