Abstract
New emission branching fraction measurements for 836 lines of the first spectrum of vanadium (V I) are determined from hollow cathode lamp spectra recorded with the National Solar Observatory 1 m Fourier transform spectrometer (FTS) and a high-resolution echelle spectrometer. The branching fractions are combined with recently published radiative lifetimes from laser-induced fluorescence measurements to determine accurate absolute atomic transition probabilities for the 836 lines. The FTS data are also used to extract new hyperfine structure A coefficients for 26 levels of neutral vanadium. These new laboratory data are applied to determine the V abundance in the Sun and metal-poor star HD 84937, yielding log epsilon(V) = 3.956 +/- 0.004 (sigma = 0.037) based on 93 V I lines and log epsilon(V) = 1.89 +/- 0.03 (sigma = 0.07) based on nine Vi lines, respectively, using the Holweger-Muller 1D model. These new V I abundance values for the Sun and HD 84937 agree well with our earlier determinations based upon V II.